public class RawPrinterHelper
    {
        // Structure and API declarions:
        [StructLayout(LayoutKind.Sequential, CharSet = CharSet.Ansi)]
        public class DOCINFOA
        {
            [MarshalAs(UnmanagedType.LPStr)]
            public string pDocName;
            [MarshalAs(UnmanagedType.LPStr)]
            public string pOutputFile;
            [MarshalAs(UnmanagedType.LPStr)]
            public string pDataType;
        }
        [DllImport("winspool.Drv", EntryPoint = "OpenPrinterA", SetLastError = true, CharSet = CharSet.Ansi, ExactSpelling = true, CallingConvention = CallingConvention.StdCall)]
        public static extern bool OpenPrinter([MarshalAs(UnmanagedType.LPStr)] string szPrinter, out IntPtr hPrinter, IntPtr pd);        [DllImport("winspool.Drv", EntryPoint = "ClosePrinter", SetLastError = true, ExactSpelling = true, CallingConvention = CallingConvention.StdCall)]
        public static extern bool ClosePrinter(IntPtr hPrinter);        [DllImport("winspool.Drv", EntryPoint = "StartDocPrinterA", SetLastError = true, CharSet = CharSet.Ansi, ExactSpelling = true, CallingConvention = CallingConvention.StdCall)]
        public static extern bool StartDocPrinter(IntPtr hPrinter, Int32 level, [In, MarshalAs(UnmanagedType.LPStruct)] DOCINFOA di);        [DllImport("winspool.Drv", EntryPoint = "EndDocPrinter", SetLastError = true, ExactSpelling = true, CallingConvention = CallingConvention.StdCall)]
        public static extern bool EndDocPrinter(IntPtr hPrinter);        [DllImport("winspool.Drv", EntryPoint = "StartPagePrinter", SetLastError = true, ExactSpelling = true, CallingConvention = CallingConvention.StdCall)]
        public static extern bool StartPagePrinter(IntPtr hPrinter);        [DllImport("winspool.Drv", EntryPoint = "EndPagePrinter", SetLastError = true, ExactSpelling = true, CallingConvention = CallingConvention.StdCall)]
        public static extern bool EndPagePrinter(IntPtr hPrinter);        [DllImport("winspool.Drv", EntryPoint = "WritePrinter", SetLastError = true, ExactSpelling = true, CallingConvention = CallingConvention.StdCall)]
        public static extern bool WritePrinter(IntPtr hPrinter, IntPtr pBytes, Int32 dwCount, out Int32 dwWritten);        // SendBytesToPrinter()
        // When the function is given a printer name and an unmanaged array
        // of bytes, the function sends those bytes to the print queue.
        // Returns true on success, false on failure.
        public static bool SendBytesToPrinter(string szPrinterName, IntPtr pBytes, Int32 dwCount)
        {
            Int32 dwError = 0, dwWritten = 0;
            IntPtr hPrinter = new IntPtr(0);
            DOCINFOA di = new DOCINFOA();
            bool bSuccess = false; // Assume failure unless you specifically succeed.            di.pDocName = "Test";
            di.pDataType = "RAW";            // Open the printer.
            if (OpenPrinter(szPrinterName.Normalize(), out hPrinter, IntPtr.Zero))
            {
                // Start a document.
                if (StartDocPrinter(hPrinter, 1, di))
                {
                    // Start a page.
                    if (StartPagePrinter(hPrinter))
                    {
                        // Write your bytes.
                        bSuccess = WritePrinter(hPrinter, pBytes, dwCount, out dwWritten);
                        EndPagePrinter(hPrinter);
                    }
                    EndDocPrinter(hPrinter);
                }
                ClosePrinter(hPrinter);
            }
            // If you did not succeed, GetLastError may give more information
            // about why not.
            if (bSuccess == false)
            {
                dwError = Marshal.GetLastWin32Error();
            }
            return bSuccess;
        }        public static bool SendFileToPrinter(string szPrinterName, string szFileName)
        {
            // Open the file.
            FileStream fs = new FileStream(szFileName, FileMode.Open);
            // Create a BinaryReader on the file.
            BinaryReader br = new BinaryReader(fs);
            // Dim an array of bytes big enough to hold the file's contents.
            Byte[] bytes = new Byte[fs.Length];
            bool bSuccess = false;
            // Your unmanaged pointer.
            IntPtr pUnmanagedBytes = new IntPtr(0);
            int nLength;            nLength = Convert.ToInt32(fs.Length);
            // Read the contents of the file into the array.
            bytes = br.ReadBytes(nLength);
            // Allocate some unmanaged memory for those bytes.
            pUnmanagedBytes = Marshal.AllocCoTaskMem(nLength);
            // Copy the managed byte array into the unmanaged array.
            Marshal.Copy(bytes, 0, pUnmanagedBytes, nLength);
            // Send the unmanaged bytes to the printer.
            bSuccess = SendBytesToPrinter(szPrinterName, pUnmanagedBytes, nLength);
            // Free the unmanaged memory that you allocated earlier.
            Marshal.FreeCoTaskMem(pUnmanagedBytes);
            return bSuccess;
        }
        public static bool SendStringToPrinter(string szPrinterName, string szString)
        {
            IntPtr pBytes;
            Int32 dwCount;
            // How many characters are in the string?
            dwCount = szString.Length;
            // Assume that the printer is expecting ANSI text, and then convert
            // the string to ANSI text.
            pBytes = Marshal.StringToCoTaskMemAnsi(szString);
            // Send the converted ANSI string to the printer.
            SendBytesToPrinter(szPrinterName, pBytes, dwCount);
            Marshal.FreeCoTaskMem(pBytes);
            return true;
        }
    }这是我在微软技术支持网站找到的代码:http://support.microsoft.com/kb/322091/en-us但是我在使用的时候却出现问题,如果使用PDF虚拟打印机,则打印任务里始终显示“已发送到打印机”,但是不打印,如果使用使用真实打印机则报错,错误原因未知!请大侠帮忙看看,直接将http://support.microsoft.com/kb/322091/en-us的代码复制到一个新工程就可以使用,你们可以试试,拜托了!